[11], Lithium chloride has been shown to have strong acaricidal properties, being effective against Varroa destructor in populations of honey bees. Inhalation: Burning sensation. Molten LiCl is used for the preparation of carbon nanotubes,[9] graphene[10] and lithium niobate. h�bbd```b``��5 ��4�d���E4�lq�x-�d���K"�w�$7����3��$S�U��)�,`��1`��`���Ge �"� �#������:@� �� endstream endobj startxref 0 %%EOF 467 0 obj <>stream Cough. Eyes: Redness. May … 1:380. Additionally, lithium chloride can itself be used as a hygrometer. The salt forms crystalline hydrates, unlike the other alkali metal chlorides. Lithium chloride 7447-41-8X -231-212-3X X XXKE-22552 U.S. Federal Regulations SARA 313 Not applicable SARA 311/312 Hazard CategoriesSee section 2 for more information CWA (Clean Water Act) Not applicable Clean Air Act Not applicable OSHA - Occupational Safety and Health Administration Not applicable CERCLA Not applicable It is used as a desiccant for drying air streams. 1989]. 1956]. Ph Eur - Find MSDS or SDS, a COA, data sheets and more information. [12], Lithium salts affect the central nervous system in a variety of ways. Lithium chloride is used as a relative humidity standard in the calibration of hygrometers. 1962, Chem. Causes redness and pain. Abdominal pain. eCl@ss 38050203 . T n��ë��>T�u#����NF���0�L����ɷ�����&��0$�ޓ�������J���M]�y������t8xu8]����"rѮ+eմ��F��S�[}|k6�m�ټ������n�2�w:��'���� ���~�Z���W�&������6�����^���NA嘃`f=.�T�j�6� *�X��`=� The salt is a typical ionic compound (with certain covalent characters) , although the small size of the Li ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties. Material Safety Data Sheet or SDS for Lithium chloride 105679 from Merck for download or viewing in the browser. 6: … 6bd�H�@1�:� Cc7�����s�L�s�4���{�iWzm�} )���� �y�. Lithium (Li) OSHA PEL N/A ACGIH TLV Not established Thionyl Chloride Aluminum Chloride (AlCl3) 1.0 ppm (4.9 3mg/m ) 2 3mg/m 1.0 ppm (4.9 3mg/m ) 2 mg/m3 Lithium Chloride Not established Not established SECTION 3 - Hazards Identification **DANGER** INTERNAL CONTENTS ARE EXTREMELY HAZARDOUS. Material Safety Data Sheet Lithium Chloride sc-203110 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Lithium Chloride STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. Lithium chloride is a chemical compound with the formula LiCl. 1960]. ��c��}��M�(�Ohv�-ʿ (�s� endstream endobj 406 0 obj <>stream ACUTE/CHRONIC HAZARDS: This compound is a mild irritant. 5.2 Special hazards arising from the substance or mixture Hydrogen chloride gas, Lithium oxides Hydrogen chloride gas, Lithium oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. h�b```�m���� ��ea��� �pP\������� 8��������6JˆF��ƈ����! Info. Lithium chloride is mainly used for the production of lithium metal by electrolysis of a LiCl/KCl melt at 450 °C (842 °F). Re: Lithium Chloride safety and alternatives CausticSymmetry on Sat Nov 14, 2015 11:23 am Pumbaa - My own success was based on internal use only, so my experience is … lithium chloride. Skin: Redness. Treatment with Pamelor could be resumed 24 hours after the last dose of linezolid or intravenous methylene blue (see WARNINGS). NACRES NA.23 Lithium chloride is also used as a flame colorant to produce dark red flames. Health Hazard SYMPTOMS: Symptoms of exposure to this compound may include vomiting, profuse diarrhea, ataxia, coma, convulsions and local irritation of the skin, eyes and mucous membranes. The salt is a typical ionic compound (with certain covalent characters) , although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.[5]. Material Safety Data Sheet Lithium chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Lithium chloride Catalog Codes: SLL1366 CAS#: 7447-41-8 RTECS: OJ5950000 TSCA: TSCA 8(b) inventory: Lithium chloride CI#: Not available. Symptoms may be delayed. [6] Mono-, tri-, and pentahydrates are known. The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Lithium chloride CAS 7447-41-8 for analysis EMSURE® ACS,Reag. Section 1: Chemical Product and Company Identification. ��0��΁���X�D��Ai��G���ʄQ�fW��v[N�DN1���@� -L����>��anl®i�1S��{�䆬�2�Vo +�#��R\&�KᙱD��Kv ��6,m��@�[��6�Lp�!��"� ix�:�r�m1���rվ�h�yM���b�U'Cɮy]4���g�P���R�N�:�Գ���X���O���x�E)���� [5] Anhydrous LiCl is prepared from the hydrate by heating with a stream of hydrogen chloride. Lithium Chloride No exposure limit established No exposure limit established Appropriate Engineering Controls : Whenever possible the use of local exhaust ventilation or other engineering controls is the preferred method of controlling exposure to airborne dust … LEAKING FLUID IS CORROSIVE. 5.2 Special hazards arising from the substance or mixture Hydrogen chloride gas, Lithium oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. Chronic toxicity symptoms following ingestion of nonlethal doses of lithium chloride with … Burning sensation. The percent relative humidity at 25 °C (77 °F) can be estimated, with minimal error in the range 10–30 °C (50–86 °F), from the following first order equation: RH=107.93-2.11C, where C is solution LiCl concentration, percent by mass. Skin burns. %PDF-1.6 %���� [5] In more specialized applications, lithium chloride finds some use in organic synthesis, e.g., as an additive in the Stille reaction. HUMAN EXPOSURE AND TOXICITY: Acute poisoning in man reported after 4 doses of 2 g each of lithium chloride, causing weakness, prostration, vertigo, and tinnitus. Irritating to eyes and skin. Cold water can be used. ��Ʉ��[H8���s\�����`���E$Y�}u1��_ Haz. May cause headache, muscle weakness and incoordination, and confusion. The equilibrium LiCl concentration in the resulting solution is directly related to the relative humidity of the air. Sore throat. 5.4 Further information No data available. Product Identification Synonyms: Lithium monochloride CAS No. Lithium chloride, anhydrous Revision Date 18-Jan-2018 Autoignition Temperature Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical ImpactNo information available Sensitivity to Static DischargeNo information available Specific Hazards Arising … Lithium chloride is a chemical compound with the formula LiCl. h��X�n7�}Iи���|�IZ�n]���om�dHJ�}�pW�ʖ��b䡅�"��f�̜��$��� m�De^y�Qx�5R()�a�P�T�P6B��H:T�P��`�ˡB/�,2Ahmx�(���R�@؂U�H^�ja��a��+Y�� D ECO #11598 P a g e 1 Material Safety Data Sheet Product Name: LITHIUM THIONYL CHLORIDE CELLS AND BATTERIES Hermetically-Sealed Lithium Thionyl Chloride Cells & Batteries All Electrochem 100, 150, 150/165MR, 180/180MR, 200/200MR series, QTC, MWD, VHT Cells and Batteries This deliquescent salt forms a self-solution when exposed to air. [7] The anhydrous salt can be regenerated by heating the hydrates. Many reactions may cause fire or explosion. eψa������5���s_��؟nڂK��YG�@�1���(c���)�%�r�7�ޤ����'��lJC��X 5�? 7447-41-8 Lithium chloride min 99% 231-212-3 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful in contact with skin and if swallowed. In developing Xenopus embryos, lithium chloride is observed to exert inhibition of GSK-3β (glycogen synthase kinase-3β), yet not reported to be a general inhibitor of other protein kinases. Series C-71. Section 3: Hazards Identification. Large doses of lithium may cause dizziness, prostration, and kidney damage. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. >V��DUg_?�ٴ�ӯu����Uq�Y ���-�:���X���%�u8�{Y}�����������s��ގ�vfY��o ���MB͊���Z� �uH�Ь�J?�/���mP8��1���4gR:͙�L��(Mj���P�s�lO��h5�枠8:=>���N��&%��+��|������Zxku|��M>FH,c`�X�`��. EC Number 231-212-3. �%��U��M�y�!K�^��5�¼�AOe��Süupk�w�Ƽ{"�Y��w�߷�浫���S/����J �('��X˘��P���� �C�T�� ��8w+���xq|.�2��"��#c�(HZ���G�S�|��N*�;� Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. Pain. Ey… In case of contact with eyes, check for wearing contact lenses and remove them immediately. One instance of reversible noticeable hepatotoxicity has been reported. 5.4 Further information No data available SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures 3 Effective date : 10.24.2014 Page 2 of 7 Lithium Chloride, Reagent Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com At 25 °C (77 °F) a saturated solution (45.8%) of the salt will yield an equilibrium relative humidity of 11.30%. For a short time in the 1940s lithium chloride was manufactured as a salt substitute, but this was prohibited after the toxic effects of the compound (tremors, fatigue, nausea) were recognized. LiCl also absorbs up to four equivalents of ammonia/mol. Also, in biochemical applications, it can be used to precipitate RNA from cellular extracts.[8]. Dehydration, weight loss, slurred speech, blurred vision, sensory loss, ataxia (failure of muscular coordination), tremors, and convulsions may occur. Lithium chloride SDS Safety Data Sheet for Lithium chloride 105679. PubChem Substance ID 24852187. Product Name: Lithium chloride. Flush eyes with running water for at least 15 minutes, keeping eyelids open. The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). words matched: chloride, Lithium SRA028 – Rainbow flames Alcohol is added to a series of beakers or crystallizing dishes containing metal salts and boric acid. (lithium, sulfuryl chloride, thionyl chloride, chlorine) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication. Boron trifluoride reacts with incandescence when heated with lithium [Merck 11th ed. Lithium chloride has been extensively tested for REACH registration Acute Effects From Overexposure: No data available for the formulation. Potential Health Effect Eye: Causes moderate eye irritation. Linear Formula LiCl . Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. (j) aspiration hazard Lithium chloride, a solid, does not present an aspiration hazard. [13][14][15], Except where otherwise noted, data are given for materials in their, ChemIDplus - 7447-41-8 - KWGKDLIKAYFUFQ-UHFFFAOYSA-M - Lithium chloride - Similar structures search, synonyms, formulas, resource links, and other chemical information, Ullmann's Encyclopedia of Industrial Chemistry, "Large-scale preparation of graphene by high temperature insertion of hydrogen into graphite", "Lithium chloride effectively kills the honey bee parasite, https://en.wikipedia.org/w/index.php?title=Lithium_chloride&oldid=996316359, Chemical articles with multiple compound IDs, Multiple chemicals in an infobox that need indexing, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, R. Vatassery, titration analysis of LiCl, sat'd in Ethanol by AgNO, This page was last edited on 25 December 2020, at 21:15. ;(Q�c+�Z�JY��V���'"�7�XJ˵��p���d~��Mt�R~���ˈY�Z>���&o�ә�9j8|��k8|��إ�s.�lw��;��h}4ҳ�Y���L`��1��ʧ��gm�_6��g����٢C�l=���8yv� ���d��%��S?�+�#�,�3�2���=JLi��w! Material Safety Data Sheet Lithium chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Lithium chloride Catalog Codes: SLL1366 CAS#: 7447-41-8 RTECS: OJ5950000 TSCA: TSCA 8(b) inventory: Lithium chloride CI#: Not available. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. N… Gives off irritating or toxic fumes (or gases) in a fire. Effects of exposure to Lithium: Fire: Flammable. Explosion: Risk of fire and explosion on contact with combustible substances and water. Lithium chloride powder, ≥99.98% trace metals basis CAS Number 7447-41-8. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Maleic anhydride decomposes explosively in the presence of lithium [Chemical Safety Data Sheet SD-88. H�̗Mk�@�����jG�o9d������B���/�@Ӕ���^���M֘���k�<3�����,N��������ԕ���F�ÇWu%����G1z�����Hp]W�����`�1uW.t�1M�i�[�� c��14��1]��ki;K�A~��Ur��L��vZ�s�=�P>�m :�YWA���at. 402 0 obj <> endobj 424 0 obj <>/Filter/FlateDecode/ID[<75F8B29C5E5C094E8E8A203404A1AD96>]/Index[402 66]/Info 401 0 R/Length 109/Prev 456671/Root 403 0 R/Size 468/Type/XRef/W[1 3 1]>>stream While the citrate, carbonate, and orotate salts are currently used to treat bipolar disorder, other lithium salts including the chloride were used in the past. LiCl is also used as a brazing flux for aluminium in automobile parts. ��u�u��f5kx��ތ�L.���b8>φ����t6?�Lnso& ��w��" Severe deep burns. No envisaged effects other than acute effects from local irritation Pain. Molecular Weight 42.39 . Lithium Coupon. [�� ����x����2L��?���j7�Ea�Px���Y�sE�GՖ6�`9b��������+��$x�i�+�{��W*n˕����b��u�R��eXKV�m��@ �S��{�U Lithium chloride lbs lbs lbs SARA Hazard Categories: Acute Chronic Flammability Pressure Reactivity Lithium chloride Clean Air Act Categories: SOCMI HAP Volatile HAP Organic HAP Ozone Depleting Lithium chloride The information presented above is offered for informational purposes only. Lithium Chloride is an antiviral metal halide utilized in a variety of assays to study cell-fate and neurobiology. COPPER CHLORIDE page 2 of 6 This Fact Sheet is a summary source of information of all potential and most severe health hazards that may result from exposure. "� �����6¿^=��}d �5A��h�{�sW��a� �?Mo4%BH�ף](O7�"B��»c�B�`L1�6� It is used as a dessicant. LITHIUM CHLORIDE . Blisters. 1. MSDS-0002 Rev. It is not toxic by ingestion, but by its corrosive nature can be irritating to the skin and eyes, it can also irritate the nostrils (National Institute for Occupational Safety and Health, 2015). (lithium, thionyl chloride) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication.. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. Shortness of breath. Jr,XH�Q��ƻ/�W�JJ���]�p��="�'�����!�jl��x��tI�G����.�E����EN�>�+J�;P�YF�T��|$��{()F%����{E���[ Y �f{BC�@تݯ5��jG׽�i��="�! Chlorine vapors and lithium react producing a luminous flame [Mellor 2, Supp. Duration of exposure, concentration of the substance Lithium Thionyl Chloride Battery Safety Data Sheet 3 May 2017 EN (English) 5/7 Aspiration hazard : Not classified Symptoms/effects after inhalation : Not expected to present a significant inhalation hazard under anticipated conditions of normal use. As with any other ionic chloride, solutions of lithium chloride can serve as a source of chloride ion, e.g., forming a precipitate upon treatment with silver nitrate: Lithium chloride is produced by treatment of lithium carbonate with hydrochloric acid. safety hazards of Copper Chloride to potentially exposed workers. NFPA SUPPLIER Santa Cruz Biotechnology, … If a battery ruptures, may be … Ingestion: Abdominal cramps. MDL number MFCD00011078. Laboured breathing. : 7447-41-8 Molecular Weight: 42.39 Chemical Formula: LiCl Product Codes: J.T. New Reagents for Selective Metalation, Deprotonation, and 1,2-Additions. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. CAS#: 7447-41-8. F3��-�5�"���:܂���.u�N�m� '0R l�;� �ü�,���8�8�:��H�} }�,@����)�����H �` E0� endstream endobj 403 0 obj <>/Metadata 16 0 R/Pages 400 0 R/StructTreeRoot 22 0 R/Type/Catalog>> endobj 404 0 obj <>/MediaBox[0 0 630 810]/Parent 400 0 R/Resources<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 405 0 obj <>stream Lithium chloride is a stable compound incompatible with strong oxidizing agents, strong acids, bromine trichloride, bromine trifluoride. Flux for aluminium in automobile parts ( c��� ) � % �r�7�ޤ����'��lJC��X 5� for! By heating the hydrates metal halide utilized in a variety of assays study! Chemical formula: LiCl Product Codes: J.T to potentially exposed workers Safety and HEALTH Data: if battery! Could be resumed 24 hours after the last dose lithium chloride hazards linezolid or intravenous methylene blue ( WARNINGS! Lithium react producing a luminous flame [ Mellor 2, Supp contact lenses and them. 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